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Article Summaries:
- Aalto University, Ruhr University Bochum, and collaborators have reported the first atomic/molecular‑layer deposition (ALD/MLD) processes using an all‑nitrogen‑coordinated cobalt complex, Co(tmsaedma)₂, as the metal precursor. Three organic linkers-hydroquinone (HQ), 1,4‑benzenedithiol (BDT), and terephthalic acid (BDC)-were employed to grow Co(II)‑organic thin films (Co‑HQ, Co‑BDT, Co‑BDC). Comprehensive X‑ray, spectroscopic, and density‑functional‑theory studies revealed stability trends (BDC > HQ > BDT) and decomposition pathways for Co‑HQ and Co‑BDT. Calcination of Co‑BDC in N₂ produced low‑density, porous CoO films with tunable structure and optical properties, demonstrating a new route to transition‑metal thin films via ALD/MLD.
Sources:
- https://semiengineering.com/three-new-ald-mld-processes-for-co-organic-thin-films-aalto-university-rub-et-al/ (Latest source article published: 2026-02-24 16:39 UTC)